Shedding light on the development of efficient blue-emitting semiconductors

Therefore, a way to reduce the energy consumption of modern white LED lights is to find better blue-emitting semiconductors. Unfortunately, no known blue-emitting compounds were simultaneously highly efficient, easily processible, durable, eco-friendly, and made from abundant materials -- until now.

In a recent study, published in Advanced Materials, a team of scientists from Tokyo Institute of Technology, Japan, discovered a new alkali copper halide, Cs₅Cu₃Cl₆I₂, that fills all the criteria. Unlike Cs₃Cu₂I₅, another promising blue-emitting candidate for future devices, the proposed compound has two different halides, chloride and iodide. Although mixed-halide materials have been tried before, Cs₅Cu₃Cl₆I₂ has unique properties that emerge specifically from the use of I⁻ and CI⁻ ions.

It turns out that Cs₅Cu₃Cl₆I₂ forms a one-dimensional zigzag chain out of two different subunits, and the links in the chain are exclusively bridged by I⁻ ions. The scientists also found another important feature: its valence band, which describes the energy levels of electrons in different positions of the material's crystalline structure, is almost flat (of constant energy). In turn, this characteristic makes photo-generated holes -- positively charged pseudoparticles that represent the absence of a photoexcited electron -- "heavier." These holes tend to become immobilized due to their strong interaction with I⁻ ions, and they easily bond with nearby free electrons to form a small system known as an exciton.

Excitons induce distortions in the crystal structure. Much like the fact that one would have trouble moving atop a suspended large net that is considerably deformed by one's own weight, the excitons become trapped in place by their own effect. This is crucial for the highly efficient generation of blue light. Professor Junghwan Kim, who led the study, explains: "The self-trapped excitons are localized forms of optically excited energy; the eventual recombination of their constituting electron-hole pair causes photoluminescence, the emission of blue light in this case."

In addition to its efficiency, Cs₅Cu₃Cl₆I₂ has other attractive properties. It is exclusively composed of abundant materials, making it relatively inexpensive. Moreover, it is much more stable in air than Cs₃Cu₂I₅ and other alkali copper halide compounds. The scientists found that the performance of Cs₅Cu₃Cl₆I₂ did not degrade when stored in air for three months, while similar light-emitting compounds performed worse after merely days. Finally, Cs₅Cu₃Cl₆I₂ does not require lead, a highly toxic element, making it eco-friendly overall.

Excited about the results of the study, Prof. Kim concludes: "Our findings provide a new perspective for the development of new alkali copper halide candidates and demonstrate that Cs₅Cu₃Cl₆I₂ could be a promising blue-emitting material." The light shed by this team of scientists will hopefully lead to more efficient and eco-friendly lighting technology.