Skin pigment could help strengthen foams, fabrics

From durable foam seating and insulation to glossy coatings and stretchy textiles, polyurethane is used in a huge range of products. Although already fairly versatile, polyurethane still has room for improvement. To make it more durable, scientists have tried adding fillers, including silica, carbon nanotubes and graphene oxide. But these efforts have often led to the enhancement of only one physical property at a time, such as tensile strength -- how hard a material can be pulled before it snaps -- but not toughness -- how much energy it can absorb without breaking. Mingqing Chen, Weifu Dong and colleagues wanted to try a new approach: adding melanin, a biomolecule increasingly used in various other materials.

The researchers found that polyurethane containing just 2 percent melanin, extracted from the ink sacs of cuttlefish, had improved tensile strength and toughness. These properties were enhanced about 10 fold, increasing from 5.6 megapascals and 33 megajoules per cubic meter in plain polyurethane to 51.5 MPa and 413 MJ/m3, respectively. Polyurethane by itself could stretch 770 percent before breaking, whereas the melanin-infused version stretched 1,880 percent before rupturing.