New, slippery toilet coating provides cleaner flushing, saves water

The possibility may exist through research conducted at Penn State, released today (Nov. 18) in Nature Sustainability.

"Our team has developed a robust bio-inspired, liquid, sludge- and bacteria-repellent coating that can essentially make a toilet self-cleaning," said Tak-Sing Wong, Wormley Early Career Professor of Engineering and associate professor of mechanical engineering and biomedical engineering.

In the Wong Laboratory for Nature Inspired Engineering, housed within the Department of Mechanical Engineering and the Materials Research Institute, researchers have developed a method that dramatically reduces the amount of water needed to flush a conventional toilet, which usually requires 6 liters.

Co-developed by Jing Wang, a doctoral graduate from Wong's lab, the liquid-entrenched smooth surface (LESS) coating is a two-step spray that, among other applications, can be applied to a ceramic toilet bowl. The first spray, created from molecularly grafted polymers, is the initial step in building an extremely smooth and liquid-repellent foundation.

"When it dries, the first spray grows molecules that look like little hairs, with a diameter of about 1,000,000 times thinner than a human's," Wang said.

While this first application creates an extremely smooth surface as is, the second spray infuses a thin layer of lubricant around those nanoscopic "hairs" to create a super-slippery surface.

"When we put that coating on a toilet in the lab and dump synthetic fecal matter on it, it (the synthetic fecal matter) just completely slides down and nothing sticks to it (the toilet)," Wang said.

With this novel slippery surface, the toilets can effectively clean residue from inside the bowl and dispose of the waste with only a fraction of the water previously needed. The researchers also predict the coating could last for about 500 flushes in a conventional toilet before a reapplication of the lubricant layer is needed.

While other liquid-infused slippery surfaces can take hours to cure, the LESS two-step coating takes less than five minutes. The researcher's experiments also found the surface effectively repelled bacteria, particularly ones that spread infectious diseases and unpleasant odors.

If it were widely adopted in the United States, it could direct critical resources toward other important activities, to drought-stricken areas or to regions experiencing chronic water scarcity, said the researchers.

Driven by these humanitarian solutions, the researchers also hope their work can make an impact in the developing world. The technology could be used within waterless toilets, which are used extensively around the world.

"Poop sticking to the toilet is not only unpleasant to users, but it also presents serious health concerns," Wong said.

However, if a waterless toilet or urinal used the LESS coating, the team predicts these types of fixtures would be more appealing and safer for widespread use.

To address these issues in both the United States and around the world, Wong and his collaborators, Wang, Birgitt Boschitsch, and Nan Sun, all mechanical engineering alumni, began a start-up venture.

With support from the Ben Franklin Technology Partners' TechCelerator, the National Science Foundation, the Department of Energy, the Office of Naval Research, the Rice Business Plan Competition and Y-Combinator, their company, spotLESS Materials, is already bringing the LESS coating to market.

"Our goal is to bring impactful technology to the market so everyone can benefit," Wong said. "To maximize the impact of our coating technology, we need to get it out of the lab."

Looking forward, the team hopes spotLESS Materials will play a role in sustaining the world's water resources and continue expanding the reach of their technology.

"As a researcher in an academic setting, my goal is to invent things that everyone can benefit from," Wong said. "As a Penn Stater, I see this culture being amplified through entrepreneurship, and I'm excited to contribute."

Other co-authors of the paper from Penn State include Lin Wang of the Department of Materials Science and Engineering; Hui Li, doctoral graduate of the Department of Biomedical Engineering; Margo Corsetti, a mechanical engineering alumna; and Pak Kin Wong, professor of biomedical engineering. International collaborators of the work include Ross Tierney, doctoral graduate, and Professor Leon Williams from Centre for Competitive Creative Design of Cranfield University, UK.

This work is supported by the National Science Foundation, the Wormley Family Early Career Professorship, and the Humanitarian Materials Initiative Award, which is funded by Covestro and the Materials Research Institute.