Wafer-thin nanopaper changes from firm to soft at the touch of a button

Inspiration from the seafloor: Mechanical switch serves a protective function

The nature-based inspiration in this case comes from sea cucumbers. These marine creatures have a special defense mechanism: When they are attacked by predators in their habitat on the seafloor, sea cucumbers can adapt and strengthen their tissue so that their soft exterior immediately stiffens. "This is an adaptive mechanical behavior that is fundamentally difficult to replicate," said Professor Andreas Walther. With their work now published, his team has succeeded in mimicking the basic principle in a modified form using an attractive material and an equally attractive switching mechanism.

The scientists used cellulose nanofibrils extracted and processed from the cell wall of trees. Nanofibrils are even finer than the microfibers in standard paper and result in a completely transparent, almost glass-like paper. The material is stiff and strong, appealing for lightweight construction. Its characteristics are even comparable to those of aluminum alloys. In their work, the research team applied electricity to these cellulose nanofibril-based nanopapers. By means of specially designed molecular changes, the material becomes flexible as a result. The process is reversible and can be controlled by an on/off switch.

"This is extraordinary. All the materials around us are not very changeable, they do not easily switch from stiff to elastic and vice versa. Here, with the help of electricity, we can do that in a simple and elegant way," said Walther. The development is thus moving away from classic static materials toward materials with properties that can be adaptively adjusted. This is relevant for mechanical materials, which can thus be made more resistant to fracture, or for adaptive damping materials, which could switch from stiff to compliant when overloaded, for example.

Targeting a material with its own energy storage for autonomous on/off switching

At the molecular level, the process involves heating the material by applying a current and thus reversibly breaking cross-linking points. The material softens in correlation with the applied voltage, i.e., the higher the voltage, the more cross-linking points are broken and the softer the material becomes. Professor Andreas Walther's vision for the future also starts at the point of power supply: While currently a power source is needed to start the reaction, the next goal would be to produce a material with its own energy storage system, so that the reaction is essentially triggered "internally" as soon as, for example, an overload occurs and damping becomes necessary. "Now we still have to flip the switch ourselves, but our dream would be for the material system to be able to accomplish this on its own."