Wearable integrated thermocells based on gel electrolytes use body heat as power source

Our muscle activity and metabolism cause our bodies to produce constant heat, some of which is released through the skin into the environment. Because of the relatively small temperature difference between skin (approximately 32 °C) and the temperature of our surroundings, it is not so easy to make use of body heat. Previous thermoelectric generators, such as those based on semiconductors, produce too little energy, are costly, or are too brittle for use in wearable systems. Thermocells with electrolyte solutions are difficult to integrate into extensive wearable systems. A team led by Jun Zhou at Huazhong University of Science and Technology (Wuhan, China) has now found a solution to this problem: thermocells with gel-based electrolytes.

The researchers are making use of the thermogalvanic effect: if two electrodes in contact with an electrolyte solution -- or an electrolyte gel -- are kept at different temperatures, a potential difference is generated. The ions of a redox pair in the electrolyte can rapidly switch between two different charge states, accepting or releasing electrons at electrodes with different temperature. In order to use this to produce a current, the scientists combined two types of cells containing two different redox pairs. Each cell consists of two tiny metal plates that act as electrodes, with an electrolyte gel in between. The first cell type contains the Fe2+/Fe3+ redox pair. The second type of cell contains the complex ions [Fe(CN)6]3-/[Fe(CN)6]4-. Because of the choice of these redox pairs, in cell type 1, the cold end gives a negative potential, while in type 2, the cold end gives a positive potential.

The researchers arranged many of these two types of cells into a checkerboard pattern. The cells were connected to each other by metal plates alternating above and below, to link them into a series. They then integrated this "checkerboard" into a glove. When the glove is worn, the desired temperature difference results between the upper and lower plates. This produces a voltage between neighboring cells, and the voltage adds up. This makes it possible to generate current to power a device or charge a battery.

In an environment at 5 °C, it was possible to produce 0.7 volts and about 0.3 μW. By optimizing this system, it should be possible to improve the power, even with smaller temperature gradients.