When the music changes, so does the dance: Controlling cooperative electronic states in Kagome metals

Named after the Japanese bamboo-basket woven pattern, a two-dimensional (2D) Kagome lattice is constructed by a series of corner-sharing triangles. When each corner is occupied with magnetic moments with antiferromagnetic correlations, the nearest-neighbor interactions favor anti-aligned spins. The system is therefore geometrically frustrated to reach a magnetically ordered state, normally referred as magnetic frustration. In the late 1980s, it was shown that the antiferromagnetic kagome lattice may be the most frustrated 2D magnetic system that one can construct [1].

A particular group of Kagome superconductors has recently attracted intense scientific debate, with a range of studies revealing apparently contradictory properties in these materials. Now an international research team led by scientists at the Max Planck Institute for the Structure and Dynamics of Matter (MPSD) in Germany has managed to investigate a member of this group of Kagome materials without external perturbations -- a crucial step in order to understand its intrinsic electronic ground state. The study has been published in Nature Physics [2].

When 2D Kagome nets are combined into 3D metals, these so-called Kagome metals become a rich testbed for exploring the interplay between non-trivial topological excitations and strong electronic correlations. Moreover, the strong geometrical frustration prevents the electronic orders from being established as multiple possible ground states are almost energetically degenerate, meaning that there exist two or more possible electronic ground states that are almost energetically equivalent. With the system's energy scale further normalized by the electronic correlations, Kagome metals often display intertwined electronic order as even negligible perturbations drastically modify their physical properties.

Due to their structural make-up and magnetic frustrations, the properties of Kagome materials react very strongly to even seemingly minor perturbations. This extreme tunability has been strongly exemplified by the recent advances in a group of Kagome superconductors, AV₃Sb₅. These materials display electronic orderings at around 100 Kelvin Celsius and a superconducting ground state with a critical temperature at ~ 3 K [3].Beyond this, an impressive set of experiments has demonstrated that ``something else'' is happening in this material, often associated with an onset temperature of T'~ 30 K [4]. Scientists are trying to understand the nature of these changes and why they occur. So far, the research results have been openly contradictory and heavily debated.

In their recently published work [2], the researchers have demonstrated that this, at first glance, contradictory state of the literature is a feature, not a bug. It is a direct consequence of the unconventional ground state of AV₃Sb₅, which features multiple intertwined electronic orders. Therefore, external perturbations such as strain or magnetic field may push the system out of its intrinsic ground state, leading to controversial experimental observations. To identify the inherent electronic ground state without perturbations, they developed a novel strain-free approach based on the focused-ion-beam technique to isolate AV₃Sb₅ from perturbations such as thermal differential strain [5]. These technical advances allowed the team to reveal the intrinsic electronic ground state unambiguously, as well as its drastic response to external perturbations in these Kagome superconductors. Their work provides a unifying picture of the controversial charge order in Kagome metals.

The easy-to-manipulate electronic orders in Kagome metals highlight the need for material control at the microscopic scale to identify emergent symmetry breaking in quantum materials. They also point towards the exciting pathway toward future electronics. Since the perturbations required to alter the electronic ground state are exceedingly small, the study offers important insights for the long-standing proposals of non-trivial electronic applications based on electronic instabilities in quantum materials. Clearly, electrons learn to dance to many tunes in Kagome structures.

The research team consisted of scientists from the MPSD and the Max Planck Institute for Chemical Physics of Solids in Germany, the University of Zurich (Switzerland) and the University of the Basque Country (Spain).

[1] V. Elser, Phys. Rev. Lett. 62, 2405 (1989).

[2] B. R. Ortiz et al., Phys. Rev. Materials 3, 094407 (2019).

[3] T. Neupert et al., Nat. Phys. 18, 137 (2022).

[4] C. Guo et al., Nature 611, 461 (2022).