Clean, sustainable fuels made 'from thin air' and plastic waste

The researchers, from the University of Cambridge, developed a solar-powered reactor that converts captured CO₂ and plastic waste into sustainable fuels and other valuable chemical products. In tests, CO₂ was converted into syngas, a key building block for sustainable liquid fuels, and plastic bottles were converted into glycolic acid, which is widely used in the cosmetics industry.

Unlike earlier tests of their solar fuels technology however, the team took CO₂ from real-world sources -- such as industrial exhaust or the air itself. The researchers were able to capture and concentrate the CO₂ and convert it into sustainable fuel.

Although improvements are needed before this technology can be used at an industrial scale, the results, reported in the journal Joule, represent another important step toward the production of clean fuels to power the economy, without the need for environmentally destructive oil and gas extraction.

For several years, Professor Erwin Reisner's research group, based in the Yusuf Hamied Department of Chemistry, has been developing sustainable, net-zero carbon fuels inspired by photosynthesis -- the process by which plants convert sunlight into food -- using artificial leaves. These artificial leaves convert CO₂ and water into fuels using just the power of the sun.

To date, their solar-driven experiments have used pure, concentrated CO₂ from a cylinder, but for the technology to be of practical use, it needs to be able to actively capture CO₂ from industrial processes, or directly from the air. However, since CO₂ is just one of many types of molecules in the air we breathe, making this technology selective enough to convert highly diluted CO₂ is a huge technical challenge.

"We're not just interested in decarbonisation, but de-fossilisation -- we need to completely eliminate fossil fuels in order to create a truly circular economy," said Reisner. "In the medium term, this technology could help reduce carbon emissions by capturing them from industry and turning them into something useful, but ultimately, we need to cut fossil fuels out of the equation entirely and capture CO₂ from the air."

The researchers took their inspiration from carbon capture and storage (CCS), where CO₂ is captured and then pumped and stored underground.

"CCS is a technology that's popular with the fossil fuel industry as a way to reduce carbon emissions while continuing oil and gas exploration," said Reisner. "But if instead of carbon capture and storage, we had carbon capture and utilisation, we could make something useful from CO₂ instead of burying it underground, with unknown long-term consequences, and eliminate the use of fossil fuels."

The researchers adapted their solar-driven technology so that it works with flue gas or directly from the air, converting CO₂ and plastics into fuel and chemicals using only the power of the sun.

By bubbling air through the system containing an alkaline solution, the CO₂ selectively gets trapped, and the other gases present in air, such as nitrogen and oxygen, harmlessly bubble out. This bubbling process allows the researchers to concentrate the CO₂ from air in solution, making it easier to work with.

The integrated system contains a photocathode and an anode. The system has two compartments: on one side is captured CO₂ solution that gets converted into syngas, a simple fuel. On the other plastics are converted into useful chemicals using only sunlight.

"The plastic component is an important trick to this system," said co-first author Dr Motiar Rahaman. "Capturing and using CO₂ from the air makes the chemistry more difficult. But, if we add plastic waste to the system, the plastic donates electrons to the CO₂. The plastic breaks down to glycolic acid, which is widely used in the cosmetics industry, and the CO₂ is converted into syngas, which is a simple fuel."

"This solar-powered system takes two harmful waste products -- plastic and carbon emissions -- and converts them into something truly useful," said co-first author Dr Sayan Kar.

"Instead of storing CO₂ underground, like in CCS, we can capture it from the air and make clean fuel from it," said Rahaman. "This way, we can cut out the fossil fuel industry from the process of fuel production, which can hopefully help us avoid climate destruction."

"The fact that we can effectively take CO₂ from air and make something useful from it is special," said Kar. "It's satisfying to see that we can actually do it using only sunlight."

The scientists are currently working on a bench-top demonstrator device with improved efficiency and practicality to highlight the benefits of coupling direct air capture with CO2 utilisation as a path to a zero-carbon future.