Uncovering the secret of ternary polymer solar cell success

PSCs generally contain a material that is the p-type semiconductor mixed with one that is the n-type semiconductor. This blend gives the right combination of charge carriers -- holes and electrons -- for a current to flow when sunlight shines on the cell.

Blends with these two components are known as binary PSCs. However, it has recently been found that adding an extra ingredient to the mix -- giving what is known as a ternary PSC -- can improve the power conversion efficiency (PCE) and stability of the solar cell. The trouble is that up until now nobody has thoroughly investigated why.

The researchers therefore conducted electron spin resonance (ESR) spectroscopy while the PSC was operating. This gave them the chance to observe the behavior of the electrons and holes when the cell was irradiated with sunlight and to get answers on a molecular level.

"It has been reported that the accumulation of charge over time contributes to the performance of cells deteriorating," explain study author Professor Itaru Osaka and study corresponding author Professor Kazuhiro Marumoto. "We therefore used ESR to look at a system made up of the polymer PTzBT and large molecule PC₆₁BM. It has been found that adding an acceptor molecule, known as ITIC, to this system improves the PCE and the stability of the cell, so we looked closely at cells with and without ITIC to determine why."

The ESR spectroscopy experiment showed that the short-circuit current decreased as a result of the accumulation of electrons in the PC₆₁BM and holes in PTzBT. Adding ITIC was found to reduce this accumulation by enhancing the orientation of the chainlike PTzBT polymer molecules in the active layer.

"Being able to understand why something works is important for ensuring that effects are optimized to their full potential," says study corresponding author Professor Kazuhiro Marumoto. "By getting a molecular level picture of the effects of ITIC on a very promising PSC system, we believe we have taken a step closer to the commercial reality of polymer solar cells as part of a greener future."

This work was partially supported by JSPS KAKENHI Grant Number JP19K21955, by JST PRESTO, by The MIKIYA Science And Technology Foundation, by Iketani Science and Technology Foundation, by The Iwatani Naoji Foundation, by JST SPRING Grant Number JPMJSP2124, by JST ALCA Grant Number JPMJAL1603, and by JST MIRAI Grant Number JPMJMI20C5, Japan.