Scientists observe record high hydride ion conductivity using modified lanthanum trihydride

In the recent past, scientists have explored multiple possibilities in an attempt to harness energy from various other sources. One such example includes the use of hydrogen-based energy systems. In this regard, lanthanum hydride, a compound of hydrogen and the metallic element lanthanum, has attracted quite a lot of attention. Because of its unique material properties, lanthanum hydride allows for superior hydride ion (H^-) conductivity under certain conditions, which is the prerequisite for the efficient operation of chemical reactors and energy storage systems. However, most H^- conductors show low H^- conductivity at room temperature, which limits their application.

In a new study, researchers from Tokyo Institute of Technology (Tokyo Tech) have now come up with a technological innovation that can be used to overcome this limitation and design the next generation of energy carriers. The research team, led by Prof. Hideo Hosono, senior author of the study and Honorary Professor, Tokyo Tech, has successfully prepared and characterized a hydrogen-rich lanthanum hydride, with the chemical formula "LaH_3−2xO_x," which shows a H^- conductivity that is higher by three orders of magnitude when compared with the best conductor available. Their trick was to control the concentration of oxygen in LaH_3−2xO_x.

The researchers used a two-step process to prepare LaH_3−2xO_x. The high-density LaH_3−2xO_x pellet prepared using the first high-pressure synthesis step had a large amount of hydrogen deficiency. Next, the researchers exposed these pellets to hydrogen gas atmosphere at an elevated temperature (400 °C) for an extended duration (10 hours) to fill the hydrogen vacancy. It resulted in the formation of "LaH_2.8O_0.1," a novel material showing high ionic conductivity even at room temperature.

Elaborating the concept behind their research, which is all set to be published in the Journal of the American Chemical Society, Prof. Hosono says, "Our study was driven by the idea that minimizing the amount of substituted O²⁻ used to suppress the electronic conduction in LaH_3−y should ideally make fast H⁻ conduction in LaH_3−2xO_x at room temperature possible."

Quite interestingly, the hydrogen-rich LaH_3−2xO_x also exhibited a low activation barrier -- an energy hurdle that it must overcome to successfully function as an efficient ionic conductor. In terms of the actual measurement, this low activation barrier was somewhere between 0.3 and 0.4 eV. Moreover, the low activation barrier was independently confirmed using computerized simulations. The simulations also showed that the H^- ions far from O²⁻ ions were highly mobile and some of them traveled long distances by knocking each other out, suggesting the presence of strong repulsive Coulombic interactions ideal for fast H^- conduction.

It seems there is good reason for Prof. Hosono to observe optimistically, "Hydrogen-rich LaH_3−2xO_x is a promising candidate for next-generation hydrogen carriers and can promote fossil fuel replacement!"