Tiny wires change behavior at nanoscale

A new study from Rice University finds gold wires less than 20 nanometers wide can become "brittle-like" under stress. It appears in the journal Advanced Functional Materials.

The paper by Rice materials scientist Jun Lou and his lab shows in microscopic detail what happens to nanowires under the kinds of strain they would reasonably undergo in, for instance, flexible electronics.

Their technique provides a way for industry to see just how nanowires made of gold, silver, tellurium, palladium and platinum are likely to hold up in next-generation nanoelectronic devices.

Lou and his team had already established that metal wires have unique properties on the nanoscale. They knew such wires undergo extensive plastic deformation and then fracture on both the micro- and nanoscale. In that process, materials under stress exhibit "necking"; that is, they deform in a specific region and then stretch down to a point before they eventually break.

"Gold is extremely ductile," said Lou, an assistant professor of mechanical engineering and materials science. "That means you can stretch it, and it can withstand very large displacement.

"But in this work, we discovered that gold is not necessarily very ductile at the nanoscale. When we stress it in a slightly different way, we can form a defect called a twin."

The term "twinning" comes from the mirrorlike atomic structure of the defect, which is unique to crystals. "At the boundary, the atoms on the left and right sides exactly mirror each other," Lou said. Twins in nanowires show up as dark lines across the wire under an electron microscope.

"The material is not exactly brittle, like glass or ceramic, which fracture with no, or very little, ductility," he said. "In this case, we call it brittle-like, which means it has significantly reduced ductility. There's still some, but the fracture behavior is different from regular necking."

Their experiments on 22 gold wires of less than 20 nanometers involved the delicate operation of clamping them to a transmission electron microscope/atomic force microscope sample holder and then pulling them at constant loading speeds. Twins appeared under the shear component of the stress, which forced atoms to shift at the location of surface defects and led to a kind of nanoscale tectonic fault across the wire.

"Once you have those kinds of damage-initiation sites formed in the nanowire, you will have a lot less ductility. The metal will fracture prematurely," Lou said. "We didn't expect such twin-boundary formations would have such profound effects."

With current technology, it's nearly impossible to align the grip points on either side of the wire, so shear force on the nanowires was inevitable. "But this kind of loading mode will inevitably be encountered in the real world," he said. "We cannot imagine all the nanowires in an application will be stressed in a perfectly uniaxial way."

Lou said the results are important to manufacturers thinking of using gold as a nanomechanical element. "Realistically, you could have some off-axis angle of stress, and if these twins form, you would have less ductility than you would expect. Then the design criteria would have to change.

"That's basically the central message of this paper: Don't be fooled by the traditional definition of 'ductile,'" he said. "At the nanoscale, things can happen differently."

Lou's team included former Rice graduate student and the paper's first author, Yang Lu, now a postdoctoral researcher at MIT. Jun Song, an assistant professor at McGill University, and Jian Yu Huang, a scientist at Sandia National Laboratories, are co-authors of the paper.