Bidding adieu to sticky ice, but with a grain of salt

But not all ice is created equal. In new research from the University of Illinois Chicago, scientists studied the stickiness of ice containing everyday contaminants such as salt, soap and alcohol. Most laboratory studies typically test ice made from pure water, but in nature, ice is seldom pure.

"Be it dirty sidewalks or the hull of Arctic-going marine ships, there's always impurities there," said senior author Sushant Anand, associate professor of mechanical and industrial engineering at UIC. "So, the natural question that comes to mind is: What is the influence of these compounds on how strongly ice sticks to surfaces?"

Anand's laboratory prepared ice with varying concentrations of contaminants and tested how strongly they clung to different industrial materials. Surprisingly, they found that impure ice was much less sticky than ice made from pure water under certain conditions.

The cause of this slipperiness was traced back to the way water freezes when it contains impurities and the unique structure where ice touches a solid material, called a quasi-liquid layer.

"The ice region near a solid has liquid-like properties, and its thickness could contribute to how tightly ice sticks," Anand said. "But this region is really difficult to analyze through experiments."

So, he teamed up with UIC colleague Subramanian Sankaranarayanan and his group at UIC/Argonne National Laboratory to study this layer and how it changes with different levels of impurities, using molecular dynamics simulations. They found that as impure water freezes, it expels contaminants that drain along channels and ice-grain boundaries toward the ice base, where it forms a liquid layer that gives ice extra slipperiness.

"These insights could lead to the design of next-generation winterization techniques that slowly release contaminants to promote facile ice shedding," said graduated PhD student Rukmava Chatterjee, first author of the paper.

The surprising test results raised another question: If small salt concentrations make ice less likely to stick to surfaces, why do ships in arctic climates that sail through salt water still struggle with ice formation?

Experiments revealed that the water freezing rate can influence how impurities migrate to regions where ice touches a solid. A slow freezing process causes the isolation of contaminants into concentrated pockets or even complete expulsion, producing purer and stronger ice. Faster freezing preserves the contaminants within the ice and their accumulation at the ice-solid interface, leading to weaker adhesion.

"Our study represents just the tip of the iceberg, opening new lines of investigation of how impure ice adheres with widespread implications across multiple disciplines," Anand said.

In addition to Anand, Chatterjee and Sankaranarayanan, UIC co-authors include Rajith Unnikrishnan Thanjukutty, Christopher Carducci, Arnab Neogi, Suman Chakraborty, Vijay Prithiv Bathey Ramesh Bapu and Suvo Banik.

The research was supported by the National Science Foundation CBET-1805753 and CBET-1847627. Simulation studies were performed at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility, and supported by the U.S. DOE, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357.