New record for carbon dioxide capture

Using a Metal Organic Frameworks (MOFs) nanocomposite that can be regenerated with remarkable speed and low energy cost, researchers have developed sponge-like technology that can capture carbon dioxide from a number of sources, even directly from air.

The magnetic sponge is used to remove carbon dioxide using the same techniques as induction cooktops using one-third of the energy than any other reported method.

Associate Professor Matthew Hill (CSIRO and Department of Chemical Engineering, Monash University) and Dr Muhammad Munir Sadiq (Department of Chemical Engineering, Monash University) led this research.

In the study, published in Cell Reports Physical Science, researchers designed a unique adsorbent material called M-74 CPT@PTMSP that delivered a record low energy cost of just 1.29 MJ kg-1CO₂ , 45 per cent below commercially deployed materials, and the best CCS efficiency recorded.

MOFs are a class of compounds consisting of metal ions that form a crystalline material with the largest surface area of any material known. In fact, MOFs are so porous that they can fit the entire surface of a football field in a teaspoon.

This technology makes it possible to store, separate, release or protect valuable commodities, enabling companies to develop high value products.

"Global concerns on the rising level of greenhouse gas emissions and the associated environmental impact has led to renewed calls for emissions reduction and the development of green and renewable alternative energy sources," Associate Professor Hill said.

"However, existing commercial carbon capture technologies use amines like monoethanolamine, which is highly corrosive, energy intensive and captures a limited amount of carbon from the atmosphere.

"Our research shows the lowest reported regeneration energy calculated for any solid porous adsorbent, including monoethanolamine, piperazine and other amines. This makes it a cheap method that can be paired with renewable solar energy to capture excess carbon dioxide from the atmosphere.

"Essentially, we can capture CO₂ from anywhere. Our current focus is for capture directly from the air in what are known as negative emissions technologies."

For MOFs to be used in CCS applications, it is essential to have materials that can be easily fabricated with good stability and performance.

The stability of M-74 CPT@PTMSP was evaluated by estimating the amount of CO₂ and H₂O captured and released via the researchers' magnetic induction swing adsorption (MISA) process over 20 consecutive cycles.

The regeneration energy calculated for M-74 CPT@PTMSP is the lowest reported for any solid porous adsorbent. At magnetic fields of 14 and 15 mT, the regeneration energy calculated for M-74 CPT was 1.29 and 1.44 MJ kg CO₂-1.