'Thermal metamaterial' innovation could help bring waste-heat harvesting technology to power plants, factories

Roughly 50 to 60 percent of the energy generated in coal and oil-based power plants is wasted as heat. However, thermophotovoltaic devices that generate electricity from thermal radiation might be adapted to industrial pipes in factories and power plants, as well as on car engines and automotive exhaust systems, to recapture much of the wasted energy.

In new findings, researchers demonstrated howto restrict emission of thermal radiation to a portion of the spectrum most needed for thermophotovoltaic technology.

"These devices require spectrally tailored thermal emission at high temperatures, and our research shows that intrinsic material properties can be controlled so that a very hot object glows only in certain colors," said Zubin Jacob, an assistant professor of electrical and computer engineering at Purdue University. "The main idea is to start controlling thermal emission at record high temperatures in ways that haven't been done before."

The thermal metamaterial -- nanoscale layers of tungsten and hafnium oxide -- was used to suppress the emission of one portion of the spectrum while enhancing emission in another. (An animation is available at https://youtu.be/mRhcNF1yyyU .)

Metamaterials are composite media that contain features, patterns or elements such as tiny nanoantennas that enable an unprecedented control of light. Under development for about 15 years, the metamaterials owe their unusual abilities to precision design and manufacture on the scale of nanometers.

"They have been used mainly to manipulate coherent light, as in a laser, but the ability to manipulate infrared thermal radiation at 1,000 C opens up new areas of research," Jacob said. "The technique we used to achieve this thermal suppression and enhancement is fundamentally different from existing thermal engineering approaches and harnesses a phenomenon called topological transitions."

Findings were detailed in a research paper published earlier this year in the journal Nature Communications. The work was performed by researchers at Purdue, the Hamburg University of Technology in Germany; University of Alberta in Canada; and Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research in Germany. The co-lead authors were Hamburg University of Technology postdoctoral researcherPavel Dyachenko and University of Alberta doctoral student Sean Molesky.

The research represents the first time the approach was used for thermal emission in high-temperature metamaterials, also called refractory metamaterials.

"My student, Sean Molesky, theoretically predicted it in 2012, and it has taken about four years and some exceptional materials engineering from our collaborators to perform the high-temperature experiments and demonstrate the thermal metamaterial," Jacob said.

The basic operating principle of a photovoltaic cell is that a semiconducting material is illuminated with light, causing electrons to move from one energy level to another. Electrons in the semiconductor occupy a region of energy called the valence band while the material is in the dark. But shining light on the material causes the electrons to absorb energy, elevating them into a region of higher energy called the conduction band. As the electrons move to the conduction band, they leave behind "holes" in the valance band. The region between both bands, where no electrons exist, is called the band gap.

"If you have energy below the band gap, that is generally wasted," Jacob said. "So what you want to do for high-efficiency thermal energy conversion is suppress the thermal emission below the band gap and enhance it above the band gap, and this is what we have done. We have used the topological transition in a way that was not done before for thermal enhancement and suppression, enhancing the high-energy part of the emission spectrum and suppressing the low-energy thermal photons. This allows us to emit light only within the energy spectrum above the band gap."

The paper's other authors were Jacob; Hamburg University of Technology researchers Alexander Yu Petrov, Slawa Lang, Manfred Eich, T. Krekeler and M. Ritter; and senior research scientist Michael Störmer from the Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research.

Future research will include work to convert heat radiation from a thermal metamaterial to electron-hole pairs in a semiconducting material, a critical step in developing the technology. The thermophotovoltaic technology might be ready for commercialization within seven years, Jacob said.

The research was funded by the German Research Foundation, National Science and Engineering Research Council of Canada, Alberta Innovates Technology Futures, and the Helmholtz-Alberta Initiative.