Carbon dioxide 'sponge' could ease transition to cleaner energy


The report on the material is one of nearly 12,000 presentations at the 248th National Meeting & Exposition of the American Chemical Society (ACS), the world's largest scientific society, taking place here through Thursday.

"The key point is that this polymer is stable, it's cheap, and it adsorbs CO₂ extremely well. It's geared toward function in a real-world environment," says Andrew Cooper, Ph.D. "In a future landscape where fuel-cell technology is used, this adsorbent could work toward zero-emission technology."

CO₂ adsorbents are most commonly used to remove the greenhouse gas pollutant from smokestacks at power plants where fossil fuels like coal or gas are burned. However, Cooper and his team intend the adsorbent, a microporous organic polymer, for a different application -- one that could lead to reduced pollution.

The new material would be a part of an emerging technology called an integrated gasification combined cycle (IGCC), which can convert fossil fuels into hydrogen gas. Hydrogen holds great promise for use in fuel-cell cars and electricity generation because it produces almost no pollution. IGCC is a bridging technology that is intended to jump-start the hydrogen economy, or the transition to hydrogen fuel, while still using the existing fossil-fuel infrastructure. But the IGCC process yields a mixture of hydrogen and CO₂ gas, which must be separated.

Cooper, who is at the University of Liverpool, says that the sponge works best under the high pressures intrinsic to the IGCC process. Just like a kitchen sponge swells when it takes on water, the adsorbent swells slightly when it soaks up CO₂ in the tiny spaces between its molecules. When the pressure drops, he explains, the adsorbent deflates and releases the CO₂­, which they can then collect for storage or convert into useful carbon compounds.

The material, which is a brown, sand-like powder, is made by linking together many small carbon-based molecules into a network. Cooper explains that the idea to use this structure was inspired by polystyrene, a plastic used in styrofoam and other packaging material. Polystyrene can adsorb small amounts of CO₂ by the same swelling action.

One advantage of using polymers is that they tend to be very stable. The material can even withstand being boiled in acid, proving it should tolerate the harsh conditions in power plants where CO₂ adsorbents are needed. Other CO₂ scrubbers -- whether made from plastics or metals or in liquid form -- do not always hold up so well, he says. Another advantage of the new adsorbent is its ability to adsorb CO₂ without also taking on water vapor, which can clog up other materials and make them less effective. Its low cost also makes the sponge polymer attractive. "Compared to many other adsorbents, they're cheap," Cooper says, mostly because the carbon molecules used to make them are inexpensive. "And in principle, they're highly reusable and have long lifetimes because they're very robust."

Cooper also will describe ways to adapt his microporous polymer for use in smokestacks and other exhaust streams. He explains that it is relatively simple to embed the spongy polymers in the kinds of membranes already being evaluated to remove CO­₂ from power plant exhaust, for instance. Combining two types of scrubbers could make much better adsorbents by harnessing the strengths of each, he explains.

The research was funded by the Engineering and Physical Sciences Research Council and E.ON Energy.