Lignin-based jet fuel packs more power for less pollution

In a study published in the journal Fuel, researchers analyzed a Washington State University-developed jet fuel based on lignin, an organic polymer that makes plants tough and woody.

Using a range of tests and predictions, the researchers examined fuel properties critical to jet engine operation, including seal swell, density, efficiency, and emissions. Their results suggest that this sustainable fuel could be mixed with other biofuels to fully replace petroleum-derived fuels.

"When we tested our lignin jet fuel, we saw some interesting results," said Bin Yang, professor with WSU's Department of Biological Systems Engineering and corresponding author on the study. "We found that it not only had increased energy density and content but also could totally replace aromatics, which are a real problem for the aviation industry."

"Aromatics are associated with increased soot emissions, as well as contrails, which are estimated to contribute more to the climate impact of aviation than carbon dioxide," said Joshua Heyne, co-author, University of Dayton scientist and current co-director of the joint WSU-Pacific Northwest National Laboratory Bioproducts Institute. "Aromatics are still used in fuel today because we do not have solutions to some of the problems they solve: they provide jet fuel with a density that other sustainable technologies do not. Most unique is their ability to swell the O-rings used to seal metal-to-metal joints, and they do this well."

"We want to fly safely, sustainably, and with the lowest impact to human health," Heyne added. "The question is, how do we do all of this as economically as possible?"

Yang developed a patented process that turns lignin from agricultural waste into bio-based lignin jet fuel. Such sustainable fuel could help the aviation industry reduce dependance on increasingly expensive fossil fuels while meeting higher environmental standards.

The WSU-developed, lignin-based fuel's properties "offer great opportunities for increasing fuel performance, higher fuel efficiency, reduced emission, and lower costs," authors wrote in Fuel. "The fact that these molecules show sealant volume swell comparable with aromatics opens the door to develop jet fuels with virtually no aromatics, very low emissions, and very high-performance characteristics."

"The lignin-based fuel we tested complements other sustainable aviation fuels by increasing the density and, perhaps most importantly, the ring-swelling potential of blends," Heyne said. "While meeting our material needs, these sustainable blends confer higher energy densities and specific energies without using aromatics."

"This process creates a cleaner, more energy-dense fuel," Yang added. "That's exactly what sustainable aviation fuels need for the future."

Additional contributors to the study include Zhibin Yang, University of Dayton; Zhangyang Xu and Maoqi Feng, WSU; John Cort, Pacific Northwest National Laboratory; and Rafal Gieleciak, Natural Resources Canada.

Yang and his team's research has been supported by the Defense Advanced Research Projects Agency through the U.S. Department of Defense, the U.S. Department of Energy's Office of Energy Efficiency & Renewable Energy, the National Science Foundation, the U.S. Department of Transportation's Sun Grant Initiative, the National Renewable Laboratory, the Joint Center for Aerospace Technology Innovation, and WSU's Bioproducts, Science and Engineering Laboratory.