Solar photons drive water off the moon

New research at the Georgia Institute of Technology indicates that ultraviolet photons emitted by the sun likely cause H₂O molecules to either quickly desorb or break apart. The fragments of water may remain on the lunar surface, but the presence of useful amounts of water on the sunward side is not likely.

The Georgia Tech team built an ultra-high vacuum system that simulates conditions in space, then performed the first-ever reported measurement of the water photodesorption cross section from an actual lunar sample. The machine zapped a small piece of the moon with ultraviolet (157 nm) photons to create excited states and watched what happened to the water molecules. They either came off with a cross section of ~ 6 x 10⁻¹⁹ cm² or broke apart with a cross section of ~ 5 x 10⁻¹⁹ cm^2.. According to the team's measurements, approximately one in every 1,000 molecules leave the lunar surface simply due to absorption of UV light.

Georgia Tech's cross section values can now be used by scientists attempting to find water throughout the solar system and beyond.

"The cross section is an important number planetary scientists, astrochemists and the astrophysics community need for models regarding the fate of water on comets, moons, asteroids, other airless bodies and interstellar grains," said Thomas Orlando, the Georgia Tech professor who led the study.

The number is relatively large, which establishes that solar UV photons are likely removing water from the moon's surface. This research, which was carried out primarily by former Georgia Tech Ph.D. student Alice DeSimone, indicates the cross sections increase even more with decreasing water coverage. That's why it's not likely that water remains intact as H₂O on the sunny side of the moon. Orlando compares it to sitting outside on a summer day.

"If a lot of sunlight is hitting me, the probability of me getting sunburned is pretty high," said Orlando, a professor in the School of Chemistry and Biochemistry and School of Physics. "It's similar on the moon. There's a fixed solar flux of energetic photons that hit the sunlit surface, and there's a pretty good probability they remove water or damage the molecules."

The result, according to Orlando, is the release of molecules such as H₂O, H₂ and OH as well as the atomic fragments H and O. The research is published in two companion articles in the Journal of Geophysical Research: Planets. The first discusses the water photodesorption. The second paper details the photodissociation of water and the O(³P_J) formation on a lunar impact melt breccia.

Orlando is the associate director of Georgia Tech's Center for Space Technology and Research (C-STAR). C-STAR is an interdisciplinary research center that serves to organize, integrate and facilitate the impact of Georgia Tech's space science and space technology research activities. The center brings together a wide range of Georgia Tech faculty, active in space science and space technology research, and functions as the Institute's focal point for growth of the space industry in the state of Georgia.