New Catalyst Paves Way For Cheap, Renewable Hydrogen

In the June 27 issue of the journal Science, James Dumesic, John Shabaker and George Huber, of the University of Wisconsin at Madison, report developing the catalyst from nickel, tin and aluminum and using it in a process called aqueous-phase reforming (APR), which converts plant byproducts to hydrogen. The process performs as well as current methods that use precious metals such as platinum, yet runs at lower temperatures and is much cleaner.

"The APR process can be used on the small scale to produce fuel for portable devices, such as cars, batteries, and military equipment," said Dumesic. "But it could also be scaled up as a hydrogen source for industrial applications, such as the production of fertilizers or the removal of sulfur from petroleum products."

The team is now collaborating with scientists at Virent Energy Systems in Wisconsin as part of a National Science Foundation (NSF) Small Business Technology Transfer (STTR) grant to develop catalysts for generating fuels from biomass.

NSF is an independent federal agency that supports fundamental research and education across all fields of science and engineering.

According to NSF's Rose Wesson, the primary objective of the foundation's small business program is to increase the incentive and opportunity for small firms to undertake cutting-edge, high-risk, high-quality research that has a high potential economic payoff if the research is successful.

"Central to the STTR program is expansion of the public-private sector partnership to include the joint venture opportunities for small business and the nation's premier nonprofit research institutions. The program's most important role is to foster the innovation necessary to meet the nation's scientific and technological challenges in the 21st century," she said.

Hydrogen is a "clean" fuel because when it burns, it combines with oxygen to form water; no toxic byproducts or greenhouse gasses are produced in the process. The APR process extracts hydrogen from a variety of biological sources, especially simple carbohydrates and sugars generated by common plants.

The precious metal platinum (Pt) is well known to be an excellent catalyst in a number of chemical reactions. It is one component in a car's catalytic converter, for example, that helps remove toxins from automobile exhaust. Yet, platinum is rare and very expensive, costing more than $17 per gram (about $8,000 per pound).

Catalytic platinum (Pt) and nickel (Ni) stand out from other metals (such as copper or iron) because they process reaction molecules much faster. But pure nickel, unlike platinum, re-combines the hydrogen product with carbon atoms to make methane, a common greenhouse gas. Dumesic and his colleagues tested over 300 catalysts to find one that could compete with platinum and perform in the APR process. Using a specially designed reactor that can test 48 samples at one time, the team finally found a match in a modified version of what researchers call a Raney-nickel catalyst, named after Murray Raney, who first patented the alloy in 1927.

Raney-nickel is a porous catalyst made of about 90 percent nickel (Ni) and 10 percent aluminum (Al). While Raney-nickel proved somewhat effective at separating hydrogen from biomass-derived molecules, the researchers improved the material's effectiveness by adding more tin (Sn), which stops the production of methane and instead generates more hydrogen. Relative to other catalysts, the Raney-NiSn can perform for long time periods (at least 48 hours) and at lower temperatures (roughly 225 degrees Celsius).

According to Dumesic, a substitute for platinum catalysts is essential for the success of hydrogen technology. "We had to find a substitute for platinum in our APR process for production of hydrogen, since platinum is rare and also employed in the anode and cathode materials of hydrogen fuel cells to be used in products such as cars or portable computers," he said.

Additional support for this research was provided by the U.S. Department of Energy (DOE) and by the Materials Research Science and Engineering Center on Nanostructured Materials and Interfaces at the University of Wisconsin, a center established and supported by NSF.