The crystal's corners: New nanowire structure has potential to increase semiconductor applications

UC's Jackson, Smith, recently graduated PhD student Melodie Fickenscher and physics doctoral student Teng Shi, as well as several colleagues from across the US and around the world recently have published the research paper "Optical, Structural and Numerical Investigations of GaAs/AlGaAs Core-Multishell Nanowire Quantum Well Tubes" in Nano Letters, a journal on nanoscience and nanotechnology published by the American Chemical Society. In the paper, the team reports that they've discovered a new structure in a semiconductor nanowire with unique properties.

"This kind of structure in the gallium arsenide/aluminum gallium arsenide system had not been achieved before," Jackson says. "It's new in terms of where you find the electrons and holes, and spatially it's a new structure."

EYES ON SIZE AND CORNERING ELECTRONS

These little structures could have a big effect on a variety of technologies. Semiconductors are at the center of modern electronics. Computers, TVs and cellphones have them. They're made from the crystalline form of elements that have scientifically beneficial electrical conductivity properties. Many semiconductors are made of silicon, but in this case they are made of gallium arsenide. And while widespread use of these thin nanowires in new devices might still be around the corner, the key to making that outcome a reality in the coming years is what's in the corner.

By using a thin shell called a quantum well tube and growing it -- to about 4 nanometers thick -- around the nanowire core, the researchers found electrons within the nanowire were distributed in an unusual way in relation to the facets of the hexagonal tube. A close look at the corners of the tube's facets revealed something unexpected -- a high concentration of ground state electrons and holes.

"Having the faceting really matters. It changes the ballgame," Jackson says. "Adjusting the quantum well tube width allows you to control the energy -- which would have been expected -- but in addition we have found that there's a highly localized ground state at the corners which then can give rise to true quantum nanowires."

The nanowires the team uses for its research are grown at the Australian National University in Canberra, Australia -- one partner in this project that extends to disparate parts of the globe.

AFFECTING THE SCIENCE OF SMALL IN A BIG WAY

The team's discovery opens a new door to further study of the fundamental physics of semiconductor nanowires. As for leading to advances in technology such as photovoltaic cells, Jackson says it's too soon to tell because quantum nanowires are just now being explored. But in a world where hundreds of dollars' worth of technology is packed into a 5-by-2.5 inch iPhone, it's not hard to see how small but powerful science comes at a premium.

The team at UC is one of only about a half dozen in the US conducting competitive research in the field. It's a relatively young discipline, too, Jackson says, and one that's moving fast. For such innovative science, he says it's important to have a collaborative effort. The team includes scientists from research centers in the Midwest, the West Coast and all the way Down Under: UC, Miami University of Ohio and Sandia National Laboratories in California here in the US; and Monash University and the Australian National University in Australia.

The team's efforts are another example of how UC not only stands out as a leader in top-notch science, but also in shaping the future of the discipline by providing its students with high-quality educational and research opportunities.

"We're training students in state-of-the-art techniques on state-of-the-art materials doing state-of-the-art physics," Jackson says. "Upon completing their education here, they're positioned to go out and make contributions of their own."

Additional contributors to the paper are Jan Yarrison-Rice of Miami University, Oxford, Ohio; Bryan Wong of Sandia National Laboratories, Livermore, Calif.; Changlin Zheng, Peter Miller and Joanne Etheridge of Monash University, Victoria, Australia; and Qiang Gao, Shriniwas Deshpande, Hark Hoe Tan and Chennupati Jagadish of the Australian National University, Canberra, Australia.