Mercury Emissions From US Fires Surprisingly High

The paper estimates that fires in the continental United States and Alaska release about 44 metric tons of mercury into the atmosphere every year. It is the first study to estimate mercury emissions for each state, based on a new computer model developed at NCAR. The authors caution that their estimates for the nation and for each state are preliminary and are subject to a 50 percent or greater margin of error. A metric ton is about 10% larger than a U.S. ton.

Mercury does not originate in fires. Instead, it comes from industrial and natural sources, often settling into soil and plant matter. Intense fires then release the mercury back into the atmosphere, where it poses a new danger because it can reach sensitive waterways and other areas.

"What we are seeing is that mercury from other sources is being deposited into the vegetation and soil and then being released back into the atmosphere, where it can travel far downwind and contaminate watersheds and fragile ecosystems," says NCAR scientist Christine Wiedinmyer, one of the study's co-authors. "It's important for federal and state officials to have this type of information and to know where mercury is coming from so they can better protect public health and the environment."

Mercury is a toxin that can threaten human health and ecosystems. Depending on its form, it can travel long distances in the atmosphere before returning to Earth through precipitation or dry deposition. It is particularly dangerous if it winds up in waterways, because it can transform into methylmercury and move up the aquatic food chain while becoming increasingly concentrated. The Environmental Protection Agency warns pregnant women and young children against consuming some types of fish and shellfish because of mercury levels.

To estimate the emissions, Wiedinmyer and NCAR scientist Hans Friedli, who co-authored the article, used satellite observations of fires, aircraft and ground-based measurements of mercury, and a new computer model of fire emissions that Wiedinmyer created. They focused on a five-year period from 2002 to 2006 and examined every state except Hawaii, for which they lacked detailed data.

The paper warns that its estimates are subject to at least a 50 percent margin of error due to imprecise information about both the exact size of fires and the amount of mercury emitted by each fire. The estimates for the nation and each state are midpoints; Alaska's emissions, for example, are likely to be from 6.3 to 18.8 tons, but 12.5 is the midpoint.

"These are initial estimates, but they clearly point to fires in certain states emitting particularly high amounts of mercury," Wiedinmyer says.

High and low emitters

Alaska, which experienced vast wildfires from 2002 to 2006, released far more mercury than other states, with California releasing the most in the continental United States. Alaska's annual emissions over the five-year period were estimated at about 12.5 metric tons. California averaged 3.4 tons, followed by Oregon (2.5 tons), Louisiana (1.95) and Florida (1.89).

Average (2002-2006) annual mercury emissions from fires for each state, and total mercury emissions for the continental United States and Alaska.

The authors also quantified emissions by regions, as defined by the National Interagency Fire Center. The Southeast, a region that encompasses 13 states and includes border states such as Kentucky and Oklahoma, emitted 14.4 tons per year--the most of any of the NIFC regions. In addition to Louisiana and Florida, three other Southern states ranked in the top ten: Georgia, Texas, and Alabama.

In contrast, states in the Midwest and Great Lakes emitted comparatively little mercury from fires. However, they could potentially be affected by emissions from western wildfires.

The emissions varied widely by season and year, depending on the extent of fires and prescribed burns. Western states in general had far higher emissions in the summer and early fall, when wildfires are more prevalent. In the Southeast, however, emissions typically peaked in the spring and fall, which may reflect prescribed burning practices in the region.

The annual average of 44 tons for fires in the United States and Alaska compares to a total of about 108 tons that is released each year from industrial sources, such as power plants, incinerators, boilers, and mines. Mercury also comes from natural sources, including volcanoes and ocean vents.

Downwind impacts?

One of the next steps for the researchers will be to examine how much mercury from fires is deposited on nearby downwind areas, compared to how much travels around the hemisphere. Most of the mercury in fire emissions is in gaseous form, traveling thousands of miles before coming down in small amounts in rain or snow. But about 15 percent of the mercury is associated with airborne particles, such as soot, some of which may fall to Earth near the fire.

"We would like to determine the risk of mercury exposure for residents who live downwind of large-scale fires," Friedli says.

The University Corporation for Atmospheric Research manages the National Center for Atmospheric Research under primary sponsorship by the National Science Foundation (NSF). Opinions, findings, conclusions, or recommendations expressed in this document are those of the author(s) and do not necessarily reflect the views of the National Science Foundation.

Reference: Christine Wiedinmyer and Hans Friedli  "Mercury Emission Estimates from Fires: An Initial Inventory for the United States" Environmental Science and Technology, October 17, 2007

The research was funded by the National Science Foundation, NCAR's principal sponsor, as well as by the Electric Power Research Institute and the Environmental Protection Agency.