Could Graphene Replace Silicon in Electronics?

Physicists at UC Riverside have demonstrated that graphene -- a one-atom thick sheet of carbon atoms arranged in hexagonal rings -- can act as an atomic-scale billiard table, with electric charges acting as billiard balls.

The finding underscores graphene's potential for serving as an excellent electronic material, such as silicon, that can be used to develop new kinds of transistors based on quantum physics. Because they encounter no obstacles, the electrons in graphene roam freely across the sheet of carbon, conducting electric charge with extremely low resistance.

The research team, led by Chun Ning (Jeanie) Lau, found that the electrons in graphene are reflected back by the only obstacle they meet: graphene's boundaries.

"These electrons meet no other obstacles and behave like quantum billiard balls," said Lau, an assistant professor who joined UCR's Department of Physics and Astronomy in 2004. "They display properties that resemble both particles and waves."

Lau observed that when the electrons are reflected from one of the boundaries of graphene, the original and reflected components of the electron can interfere with each other, the way outgoing ripples in a pond might interfere with ripples reflected back from the banks.

Her lab detected the "electronic interference" by measuring graphene's electrical conductivity at extremely low (0.26 Kelvin) temperatures. She explained that at such low temperatures the quantum properties of electrons can be studied more easily.

"We found that the electrons in graphene can display wave-like properties, which could lead to interesting applications such as ballistic transistors, which is a new type of transistor, as well as resonant cavities for electrons," Lau said. She explained that a resonant cavity is a chamber, like a kitchen microwave, in which waves can bounce back and forth.

In their experiments, Lau and her colleagues first peeled off a single sheet of graphene from graphite, a layered structure consisting of rings of six carbon atoms arranged in stacked horizontal sheets. Next, the researchers attached nanoscale electrodes to the graphene sheet, which they then refrigerated in a cooling device. Finally, they measured the electrical conductivity of the graphene sheet.

Graphene, first isolated experimentally less than three years ago, is a two-dimensional honeycomb lattice of carbon atoms, and, structurally, is related to carbon nanotubes (tiny hollow tubes formed by rolling up sheets of graphene) and buckyballs (hollow carbon molecules that form a closed cage).

Scientifically, it has become a new model system for condensed-matter physics, the branch of physics that deals with the physical properties of solid materials. Graphene enables table-top experimental tests of a number of phenomena in physics involving quantum mechanics and relativity.

Bearing excellent material properties, such as high current-carrying capacity and thermal conductivity, graphene ideally is suited for creating components for semiconductor circuits and computers. Its planar geometry allows the fabrication of electronic devices and the tailoring of a variety of electrical properties. Because it is only one-atom thick, it can potentially be used to make ultra-small devices and further miniaturize electronics.

Study results appear in Science on September 14.

Lau, whose research focuses on nanowires, carbon nanotubes, graphene and other organic molecules, was joined in the research by UCR's Feng Miao, Sithara Wijeratne, Wenzhong Bao, Yong Zhang and Ulas C. Coskun. The research was performed at UCR. Currently, Zhang is at Southwest University, China; Coskun is at Duke University, N.C.

UCR startup funds and the UCR Center for Nanoscale Science and Engineering supported the research.