New! Sign up for our free email newsletter.
Science News
from research organizations

Polymer coating accelerates fuel production

Date:
August 5, 2021
Source:
University of Tsukuba
Summary:
Researchers have found that introducing a polymer coating onto a tin catalyst accelerated the conversion of a greenhouse gas (CO2) into an industrial fuel (formate). Computational and electrochemical investigations supported a mechanism wherein a complete polymer layer surrounding the porous tin catalysts effectively captured and shuttled CO2 molecules to the catalytically active metal surface. This simple catalyst design strategy can be applied to develop CO2-recycling systems.
Share:
FULL STORY

It is well-established that the accumulation of greenhouse gases, like carbon dioxide (CO2), in the atmosphere contributes to climate change. Therefore, CO2 capture and recycling are vital for mitigating detrimental environmental effects and addressing the climate crisis. Recently, researchers from Japan designed a polymer-coated metal catalyst that accelerates CO2 conversion and offers green energy insights.

In a study published in ACS Catalysis, researchers from the University of Tsukuba describe porous tin (Sn) catalysts coated with polyethylene glycol (PEG) and show how this polymer facilitates CO2 transformation into a useful carbon-based fuel.

Various polymers can capture CO2 molecules, and Sn catalysts are known to reduce CO2 to other molecules, like formate (HCOO-), which can be reused to power fuel cells.

"We were interested in combining these capabilities into a single catalytic system that could scrub CO2 from its surroundings and recycle it into formate," says research group leader, Professor Yoshikazu Ito. "However, it's difficult to obtain only the desired product, formate, at a high production rate and in high yield, so we had to fine-tune the catalyst design."

The formate production rate of PEG-coated Sn was 24 times higher than that of a conventional Sn plate electrode, and no byproducts were detected (>99% yield of formate). To understand this enhanced CO2-reduction reaction, the researchers fabricated an Sn catalyst coated with another CO2-capturing polymer (polyethyleneimine; PEI) whose structure interacts differently with incoming CO2. The PEG-coated Sn still outperformed the PEI-coated Sn, and considering the chemical characteristics of these polymers, the authors proposed that PEI held the CO2 molecules too tightly, whereas PEG struck a key balance in capturing and then releasing CO2 to the catalytic Sn core.

"Modeling this reaction using theoretical computations confirmed the favorability of PEG shuttling CO2 to the Sn center and explained the accelerated formate production," explains PhD student, Samuel Jeong. "However, we wanted to further clarify the PEG-CO2 interactions."

More detailed computations revealed that while the absence of polymer limits the Sn catalyst's CO2-capture ability, an excessively dense layer of PEG inhibits CO2 transfer to the metal surface, thereby decreasing formate production. Therefore, a complete but relatively sparse layer of PEG is optimal for funneling CO2 to Sn, while maintaining a CO2-rich environment and preventing byproduct release.

The mantra "reduce, reuse, recycle" no longer only refers to single-use plastics. The simple catalyst-coating technique reported by Ito and co-workers can be used to develop systems that efficiently recycle CO2 into useful compounds, like formate, which can power fuel cell devices that provide green electricity.


Story Source:

Materials provided by University of Tsukuba. Note: Content may be edited for style and length.


Journal Reference:

  1. Samuel Jeong, Tatsuhiko Ohto, Tomohiko Nishiuchi, Yuki Nagata, Jun-ichi Fujita, Yoshikazu Ito. Polyethylene Glycol Covered Sn Catalysts Accelerate the Formation Rate of Formate by Carbon Dioxide Reduction. ACS Catalysis, 2021; 9962 DOI: 10.1021/acscatal.1c02646

Cite This Page:

University of Tsukuba. "Polymer coating accelerates fuel production." ScienceDaily. ScienceDaily, 5 August 2021. <www.sciencedaily.com/releases/2021/08/210805133758.htm>.
University of Tsukuba. (2021, August 5). Polymer coating accelerates fuel production. ScienceDaily. Retrieved October 31, 2024 from www.sciencedaily.com/releases/2021/08/210805133758.htm
University of Tsukuba. "Polymer coating accelerates fuel production." ScienceDaily. www.sciencedaily.com/releases/2021/08/210805133758.htm (accessed October 31, 2024).

Explore More

from ScienceDaily

RELATED STORIES