New quantum phenomena in graphene superlattices

Quantum theory is the study of physics at the atomic and sub atomic level. It quantises energy and momentum and shows how objects are characterised as both particles and waves. Quantum oscillations can be used to map the properties of new materials in the presence of a magnetic field. This paper shows how it is possible to tune the magnetic field applied to a heterostructure comprising of graphene and boron nitride to create a whole host of different electronic materials.

The superlattice, created in graphene by its exact placement with regards to a periodically arranged boron nitride layer, interacts with the magnetic field in such a way that it is possible to tune its oscillation to manufacture bands and gaps in its electronics structure -- meaning that the magnetic field can be used to tune the materials to be metallic, semiconducting or conducting.

Andre Geim, a leading member of the team and the 2010 Nobel Laureate, says "Oscillatory quantum effects always present milestones in our understanding of materials properties. They are exceedingly rare. It is more than 30 years since a new type of quantum oscillation was reported." He added "Our oscillations stand out by their extreme robustness, happening under ambient conditions in easily accessible magnetic fields."

This work also sheds further light on Hofstadter's butterfly, a fractal pattern that describes the behaviour of electrons in a magnetic field, measured experimentally for the first time in 2013 using a graphene and boron-nitride heterostructure. In the original theoretical work on which Hofstadter's butterfly is based the electrons modelled to create the fractal pattern were treated as Bloch electrons (electrons that do not interact with one another and move within a periodic electric potential within a lattice). The research shown here illustrates how these complex fractal patterns can be viewed as Langmuir quantisation which is the quantisation of cyclotron orbits (taking what is normally thought of as a circular orbit and instead viewing it as linear)

Professor Vladimir Falko, Director of the National Graphene Institute commented "Our work helps to demystify the Hofstadter butterfly. The complex fractal structure of the Hofstadter butterfly spectrum can be understood as simple Landau quantisation in the sequence of new metals created by magnetic field."

Professor Bart van Wees, Head of the Physics of Nanodevices group at the Zernike Institute for Advanced Materials, Groningen, The Netherlands added "We have always considered quantum oscillations as very brittle, easily destroyed at higher temperatures but the authors have shown that these can now be observed at room temperature, or even higher. This is good news for possible new applications of these and other systems which are based on Van der Waals stacking of two-dimensional materials."