Lightning reshapes rocks at the atomic level

Using extremely high-resolution microscopy, Gieré, professor and chair of the Department of Earth and Environmental Science in Penn's School of Arts & Sciences, and his coauthors found that not only had the lightning melted the rock's surface, resulting in a distinctive black "glaze," but had transferred enough pressure to deform a thin layer of quartz crystals beneath the surface, resulting in distinct atomic-level structures called shock lamellae.

Prior to this study, the only natural events known to create this type of lamellae were meteorite impacts.

"I think the most exciting thing about this study is just to see what lightning can do," Gieré said. "To see that lightning literally melts the surface of a rock and changes crystal structures, to me, is fascinating."

Gieré said the finding serves as a reminder to geologists not to rush to interpret shock lamellae as indicators of a meteorite strike.

"Most geologists are careful; they don't just use one observation," he said, "But this is a good reminder to always use multiple observations to draw big conclusions, that there are multiple mechanisms that can result in a similar effect."

Gieré collaborated on the study with Wolfhard Wimmenauer and Hiltrud Müller-Sigmund of Albert-Ludwigs-Universität, Richard Wirth of GeoForschungsZentrum Potsdam and Gregory R. Lumpkin and Katherine L. Smith of the Australian Nuclear Science and Technology Organization.

The paper was published in the journal American Mineralogist.

Geologists have long known that lightning, through rapid increases in temperature as well as physical and chemical effects, can alter sediments. When it strikes sand, for example, lightning melts the grains, which fuse and form glass tubes known as fulgurites.

Fulgurites can also form when lightning strikes other materials, including rock and soil. The current study examined a rock fulgurite found near Les Pradals, France. Gieré and colleagues took samples from the rock, then cut thin sections and polished them.

Under an optical microscope, they found that the outer black layer -- the fulgurite itself -- appeared shiny, "almost like a ceramic glaze," Gieré said.

The layer was also porous, almost like a foam, due to the lightning's heat vaporizing the rock's surface. A chemical analysis of the fulgurite layer turned up elevated levels of sulfur dioxide and phosphorus pentoxide, which the researchers believe may have derived from lichen living on the rock's surface at the time of the lightning strike.

The team further studied the samples using a transmission electron microscope, which allows users to examine specimens at the atomic level. This revealed that the fulgurite lacked any crystalline structure, consistent with it representing a melt formed through the high heat from the lightning strike.

But, in a layer of the sample immediately adjacent to the fulgurite, slightly deeper in the rock, the researchers spotted an unusual feature: a set of straight, parallel lines known as shock lamellae. This feature occurs when the crystal structure of quartz or other minerals deform in response to a vast wave of pressure.

"It's like if someone pushes you, you rearrange your body to be comfortable," Gieré said. "The mineral does the same thing."

The lamellae were present in a layer of the rock only about three micrometers wide, indicating that the energy of the lightning bolt's impact dissipated over that distance.

This characteristic deformation of crystals had previously only been seen in minerals from sites where meteorites struck. Shock lamellae are believed to form at pressures up to more than 10 gigapascals, or with 20 million times greater force than a boxer's punch.

Gieré and colleagues hope to study rock fulgurites from other sites to understand the physical and chemical effects of lightning bolts on rocks in greater detail.

Another takeaway for geologists, rock climbers and hikers who spend time on rocks in high, exposed places is to beware when they see the tell-tale shiny black glaze of a rock fulgurite, as it might indicate a site prone to lightning strikes.

"Once it was pointed out to me, I started seeing it again and again," he said. "I've had some close calls with thunderstorms in the field, where I've had to throw down my metal instruments and run."

The study was supported in part by the Australian Nuclear Science and Technology Organization.