Method for detecting extremely rare inert gas isotopes for water dating

The results of the research were published in the journal Geophysical Research Letters.

The most well-known example of age determination using radioactive isotopes is radiocarbon dating, which is used for dating organic material in the environment as well as for archaeological finds. Similarly, the abundance of radioactive isotopes of the inert gases argon and krypton can be used to determine when groundwater, deep ocean water or glacial ice formed. To detect and isolate the rare atoms from water, innovative experimental methods are used that were developed and perfected in the course of basic research on quantum mechanical systems. Scientists at the Kirchhoff Institute for Physics and the Institute of Environmental Physics at Heidelberg University were now able for the first time to use the method known as Atom Trap Trace Analysis (ATTA) to date groundwater using ³⁹Ar.

Members of the environmental physics working group headed by Prof. Dr. Werner Aeschbach-Hertig first isolated pure argon from over 1,000 litres of groundwater. Using a specially developed ATTA apparatus, the team of Prof. Dr. Markus Oberthaler at the Kirchhoff Institute "trapped" the ³⁹Ar atoms and detected each one. The scientists underscore that this achievement, which culminates years of joint development work, now opens the door to a multitude of new applications for ³⁹Ar dating. "The project is an outstanding example of how methods developed in basic research of quantum mechanical properties can open up new application horizons," explains Prof. Oberthaler. The study's primary author, Dr. Florian Ritterbusch, is convinced that the measurement method can be made even better: "In principle, a litre of water should be enough for a measurement." These advances should soon make possible the first measurements of ³⁹Ar in glacial ice in the Alps. The researchers also believe that ³⁹Ar has the greatest potential in the study of deep water circulation in the ocean. "To do that we have to be able to take sufficiently accurate measurements from samples of less than ten litres of water," says Prof. Aeschbach-Hertig.

The pioneers of the new method from the Argonne National Laboratory in the U.S. organised a special ATTA workshop in Chicago in 2012 to discuss possible applications of krypton isotopes in the earth and environmental sciences. The Heidelberg ATTA collaboration is organising another such gathering to be held in March 2015. The progress made in Heidelberg in working with ³⁹Ar once again considerably broadened the range of applications, as the researchers emphasise. "The new method also represents an innovative expansion of the strong competence in isotope and dating methods that is present in Heidelberg and concentrated at the Heidelberg Center for the Environment," says Prof. Aeschbach-Hertig.